reversible
(adjective)
Capable of returning to the original state without consumption of free energy and increase of entropy.
Examples of reversible in the following topics:
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A Physical Aside: Einstein coefficients
- Because quantum mechanics for the most part is time reversible, the cross-section for the forward and reverse reactions are related.
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Carnot Cycles
- The Carnot cycle is the most efficient cyclical process possible and uses only reversible processes through its cycle.
- What is crucial to the Carnot cycle is that only reversible processes are used.
- Obviously, then, reversible processes are superior.
- Recall that both isothermal and adiabatic processes are, in principle, reversible .
- PV diagram for a Carnot cycle, employing only reversible isothermal and adiabatic processes.
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What is Entropy?
- We noted that for a Carnot cycle, and hence for any reversible processes, Qc/Qh=Tc/Th.
- Rearranging terms yields $\frac{Q_c}{T_c} = \frac{Q_h}{T_h}$ for any reversible process.
- This ratio of Q/T is defined to be the change in entropy ΔS for a reversible process,
- PV diagram for a Carnot cycle, employing only reversible isothermal and adiabatic processes.
- Calculate the total change in entropy for a system in a reversible process
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The Second Law
- If the process can go in only one direction, then the reverse path differs fundamentally and the process cannot be reversible.
- Furthermore, mechanical energy, such as kinetic energy, can be completely converted to thermal energy by friction, but the reverse is impossible.
- The Second Law of Thermodynamics(first expression): Heat transfer occurs spontaneously from higher- to lower-temperature bodies but never spontaneously in the reverse direction.
- The reverse process is impossible.
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Helical Motion
- If field strength increases in the direction of motion, the field will exert a force to slow the charges (and even reverse their direction), forming a kind of magnetic mirror.
- This force slows the motion along the field line and here reverses it, forming a "magnetic mirror. "
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Charging a Battery: EMFs in Series and Parallel
- When it is reversed, it produces an emf that opposes the other, and results in a difference between the two voltage sources .
- The charger must have a larger emf than the battery to reverse current through it.
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Stastical Interpretation of Entropy
- The most disorderly possibilities are 3 heads and 2 tails and its reverse.
- (They are the least structured. ) The most disorderly possibilities are also the most likely, with 20 out of 32 possibilities for the 3 heads and 2 tails and its reverse.
- The reverse can happen, but it is unlikely.
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Geomagnetism
- These events are called geomagnetic reversals.
- Reversals occur at apparently random intervals ranging from less than 0.1 million years to as much as 50 million years.
- The most recent such event, called the Brunhes-Matuyama reversal, occurred about 780,000 years ago.
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Photon Interactions and Pair Production
- The reverse process is also possible.
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NMR and MRIs
- This electromagnetic field has just the right frequency (known as the resonance frequency) to become absorbed and then reverse the rotation of the hydrogen protons in the magnetic field.