high-temperature superconductors
(noun)
Materials that behave as superconductors at unusually high temperatures (above about 30 K).
Examples of high-temperature superconductors in the following topics:
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Temperature and Superconductivity
- When a superconductor is placed in a weak external magnetic field H, and cooled below its transition temperature, the magnetic field is ejected.
- Usually, conventional superconductors have critical temperatures ranging from around 20 K to less than 1 K.
- High-temperature superconductors can have much higher critical temperatures.
- For example, YBa2Cu3O7, one of the first cuprate superconductors to be discovered, has a critical temperature of 92 K; mercury-based cuprates have been found with critical temperatures in excess of 130 K.
- Describe behaviors of a superconductor below a critical temperature and in a weak external magnetic field
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X-Ray Spectra: Origins, Diffraction by Crystals, and Importance
- For example, current research in high-temperature superconductors involves complex materials whose lattice arrangements are crucial to obtaining a superconducting material.
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Dependence of Resistance on Temperature
- Resistivity and resistance depend on temperature with the dependence being linear for small temperature changes and nonlinear for large.
- Some materials can become superconductors (zero resistivity) at very low temperatures (see ).
- The temperature coefficient is typically +3×10−3 K−1 to +6×10−3 K−1 for metals near room temperature.
- The resistance of a sample of mercury is zero at very low temperatures—it is a superconductor up to about 4.2 K.
- Compare temperature dependence of resistivity and resistance for large and small temperature changes
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Absolute Temperature
- Absolute temperature is the most commoly used thermodyanmic temperature unit and is the standard unit of temperature.
- Thermodynamic temperature is the absolute measure of temperature.
- By using the absolute temperature scale (Kelvin system), which is the most commonly used thermodynamic temperature, we have shown that the average translational kinetic energy (KE) of a particle in a gas has a simple relationship to the temperature:
- The kelvin (or "absolute temperature") is the standard thermodyanmic temperature unit.
- Real gases do not always behave according to the ideal model under certain conditions, such as high pressure.
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Heat as Energy Transfer
- The transfer of energy is caused by the temperature difference, and ceases once the temperatures are equal .
- Heat is often confused with temperature.
- For example, we may say the heat was unbearable, when we actually mean that the temperature was high.
- Heat is a form of energy, whereas temperature is not.
- Such a temperature increase is observed while cooking.
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Thermal Pollution
- Thermal pollution is the degradation of water quality by any process that changes ambient water temperature.
- When water used as a coolant is returned to the natural environment at a higher temperature, the change in temperature decreases oxygen supply, and affects ecosystem composition.
- Water, with its high heat capacity, works extremely well as a coolant.
- Elevated water temperature typically decreases the level of dissolved oxygen of water.
- Many aquatic species will also fail to reproduce at elevated temperatures.
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Overview of Temperature and Kinetic Theory
- Kinetic theory explains macroscopic properties of gases (such as pressure, temperature, and volume) by considering their molecular composition and motion.
- Also, the temperature of an ideal monatomic gas is a measure of the average kinetic energy of its atoms, as illustrated in .
- The kinetic theory of gases uses the model of the ideal gas to relate temperature to the average translational kinetic energy of the molecules in a container of gas in thermodynamic equilibrium .
- In kinetic theory, the temperature of a classical ideal gas is related to its average kinetic energy per degree of freedom Ek via the equation:
- Real gases do not always behave according to the ideal model under certain conditions, such as high pressure.
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Diffusion
- Diffusion is the movement of particles from regions of high concentration towards regions of lower concentration.
- Diffusion is the movement of particles move from an area of high concentration to an area of low concentration until equilibrium is reached .
- Molecular diffusion, often called simply diffusion, is the thermal motion of all (liquid or gas) particles at temperatures above absolute zero.
- The rate of this movement is a function of temperature, viscosity of the fluid and the size (mass) of the particles.
- Particles moving from areas of high concentration to areas of low concentration.
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Conduction
- The heat flux thus depends on the temperature difference T=Thot−Tcold.
- The temperature of the material is T2 on the left and T1 on the right, where T2 is greater than T1.
- he molecules in two bodies at different temperatures have different average kinetic energies.
- Collisions occurring at the contact surface tend to transfer energy from high-temperature regions to low-temperature regions.
- In contrast, a molecule in the higher temperature region (left side) has high energy before collision, but its energy decreases after colliding with the contact surface.
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Humidity, Evaporation, and Boiling
- Because evaporation is inhibited by high humidity, we feel hotter at a given temperature when the humidity is high.
- The amount of water vapor the air can hold depends on its temperature.
- The liquid and solid phases are continuously giving off vapor because some of the molecules have high enough speeds to enter the gas phase, a process called evaporation; see (a).
- Since the kinetic energy of a molecule is proportional to its temperature, evaporation proceeds more quickly at higher temperatures.
- Vapor pressure increases with temperature because molecular speeds are higher as temperature increases.