pH indicator
(noun)
An acid-base indicator.
Examples of pH indicator in the following topics:
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Acid-Base Indicators
- For applications requiring precise measurement of pH, a pH meter is frequently used.
- These commercial indicators (e.g., universal indicator and Hydrion papers) are used when only rough knowledge of pH is necessary.
- For example, phenol red exhibits an orange color between pH 6.8 and pH 8.4.
- Therefore, you would want an indicator to change in that pH range.
- Common indicators for pH indication or titration endpoints is given, with high, low, and transition pH colors.
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Acid-Base Titrations
- strong acid-weak base titration: methyl orange indicator the base is off the scale (e.g., pH > 13.5) and the acid has pH > 5.5: alizarine yellow indicator
- the base is off the scale (e.g., pH > 13.5) and the acid has pH > 5.5: alizarine yellow indicator
- the base is off the scale (e.g., pH > 13.5) and the acid has pH > 5.5: alizarine yellow indicator
- the acid is off the scale (e.g., pH < 0.5) and the base has pH < 8.5: thymol blue indicator
- You can determine the pH of a weak acid solution being titrated with a strong base solution at various points; these fall into four different categories: (1) initial pH; (2) pH before the equivalence point; (3) pH at the equivalence point; and (4) pH after the equivalence point.
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pH, Buffers, Acids, and Bases
- Acids dissociate into H+ and lower pH, while bases dissociate into OH- and raise pH; buffers can absorb these excess ions to maintain pH.
- Human cells and blood each maintain near-neutral pH.
- The pH of a solution indicates its acidity or basicity (alkalinity).
- This diagram shows the body's buffering of blood pH levels: the blue arrows show the process of raising pH as more CO2 is made; the purple arrows indicate the reverse process, lowering pH as more bicarbonate is created.
- The pH scale measures the concentration of hydrogen ions (H+) in a solution.
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Weak Bases
- Both actions raise the pH of the solution by decreasing the concentration of H+ ions.
- The pH of bases in aqueous solution ranges from greater than 7 (the pH of pure water) to 14 (though some bases have pH values greater than 14).
- The formula for pH is:
- Sometimes, however, it is more convenient to focus on the pOH of bases, rather than the pH.
- Smaller pKb values indicate higher values of Kb; this also indicates a stronger base.
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Weak Acid-Strong Base Titrations
- A weak acid will react with a strong base to form a basic (pH > 7) solution.
- The titration curve demonstrating the pH change during the titration of the strong base with a weak acid shows that at the beginning, the pH changes very slowly and gradually.
- When the NaOH is in excess, the pH change is the same as in any system dominated by NaOH.
- However, the pH at the equivalence point does not equal 7.
- This figure depicts the pH changes during a titration of a weak acid with a strong base.
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Strong Acid-Weak Base Titrations
- A strong acid will react with a weak base to form an acidic (pH < 7) solution.
- A known volume of base with unknown concentration is placed into an Erlenmeyer flask (the analyte), and, if pH measurements can be obtained via electrode, a graph of pH vs. volume of titrant can be made (titration curve).
- As the equivalence point is approached, the pH will change more gradually, until finally one drop will cause a rapid pH transition through the equivalence point.
- In strong acid-weak base titrations, the pH at the equivalence point is not 7 but below it.
- A depiction of the pH change during a titration of HCl solution into an ammonia solution.
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The Effect of pH on Solubility
- By changing the pH of the solution, you can change the charge state of the solute.
- The pH of an aqueous solution can affect the solubility of the solute.
- By changing the pH of the solution, you can change the charge state of the solute.
- As it migrates through a gradient of increasing pH, however, the protein's overall charge will decrease until the protein reaches the pH region that corresponds to its pI.
- Describe the effect of pH on the solubility of a particular molecule.
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Microbial Growth at Low or High pH
- Pure water has a pH very close to 7 at 25°C.
- Solutions with a pH less than 7 are said to be acidic, and solutions with a pH greater than 7 are said to be basic or alkaline .
- The pH scale is traceable to a set of standard solutions whose pH is established by international agreement.
- Neutrophiles are organisms that thrive in neutral (pH 7) environments; extromophiles are organisms that thrive in extreme pH environments.
- A pH scale with annotated examples of chemicals at each integer pH value
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The Henderson-Hasselbalch Equation
- The equation is also useful for estimating the pH of a buffer solution and finding the equilibrium pH in an acid-base reaction.
- $-p{ K }_{ a }=-pH+log(\frac { [A^{ - }] }{ [HA] } )$
- $pH=p{ K }_{ a }+log(\frac { { [A }^{ - }] }{ [HA] } )$
- ${ 10 }^{ pH-p{ K }_{ a } }=\frac { [base] }{ [acid] }$
- $pH=p{ K }_{ a }+log(\frac { { [NH_3}] }{ [NH_4^+] } )$
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Buffers Containing a Base and Conjugate Acid
- Reactions with weak bases result in a relatively low pH compared to strong bases.
- Bases range from a pH of greater than 7 (7 is neutral like pure water) to 14 (though some bases are greater than 14).
- The pH of bases is usually calculated using the OH- concentration to find the pOH first.
- Calculate the pH of a buffer solution consisting of 0.051 M NH3 and 0.037 M NH4+.
- Calculate the pH of an alkaline buffer system consisting of a weak base and its conjugate acid.