chemical reaction
Physics
Chemistry
Examples of chemical reaction in the following topics:
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Energy Changes in Chemical Reactions
- Due to the absorption of energy when chemical bonds are broken, and the release of energy when chemical bonds are formed, chemical reactions almost always involve a change in energy between products and reactants.
- By the Law of Conservation of Energy, however, we know that the total energy of a system must remain unchanged, and that oftentimes a chemical reaction will absorb or release energy in the form of heat, light, or both.
- The energy change in a chemical reaction is due to the difference in the amounts of stored chemical energy between the products and the reactants.
- This stored chemical energy, or heat content, of the system is known as its enthalpy.
- Describe the types of energy changes that can occur in chemical reactions
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Introduction to Chemical Reactivity
- Now that we can recognize these actors ( compounds ), we turn to the roles they are inclined to play in the scientific drama staged by the multitude of chemical reactions that define organic chemistry.
- Chemical Reaction: A transformation resulting in a change of composition, constitution and/or configuration of a compound (referred to as the reactant or substrate).
- Reactant or Substrate: The organic compound undergoing change in a chemical reaction.
- Reagent: A common partner of the reactant in many chemical reactions.
- Catalysts are substances that accelerate the rate ( velocity ) of a chemical reaction without themselves being consumed or appearing as part of the reaction product.
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Amount of Reactants and Products
- Stoichiometry is the study of the relative quantities of reactants and products in chemical reactions and how to calculate those quantities.
- Chemical equations are symbolic representations of chemical reactions.
- The numerical coefficients next to each chemical entity denote the proportion of that chemical entity before and after the reaction.
- The law of conservation of mass dictates that the quantity of each element must remain unchanged in a chemical reaction.
- Reaction stoichiometry describes the quantitative relationship among substances as they participate in various chemical reactions.
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Free Energy
- Since chemical reactions release energy when energy-storing bonds are broken, how is the energy associated with chemical reactions quantified and expressed?
- Every chemical reaction involves a change in free energy, called delta G (∆G).
- These chemical reactions are called endergonic reactions; they are non-spontaneous.
- Therefore, the chemical reactions involved in anabolic processes are endergonic reactions.
- Most chemical reactions are reversible.
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Changes in Temperature
- Changes in temperature shift the equilibrium state of chemical reactions; these changes can be predicted using Le Chatelier's Principle.
- Changes in temperature can affect the equilibrium state of a reversible chemical reaction.
- Le Chatelier's Principle states that when changes are made to a reversible chemical reaction in equilibrium, the system will compensate for that change with a predictable, opposing shift.
- Reactions can be classified by their enthalpies of reaction.
- Evaluate the effect of temperature on the equilibrium state of a chemical reaction
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Chemical Reactions and Molecules
- Chemical reactions occur when two or more atoms bond together to form molecules or when bonded atoms are broken apart.
- Chemical reactions occur when two or more atoms bond together to form molecules or when bonded atoms are broken apart.
- The substances used in the beginning of a chemical reaction are called the reactants (usually found on the left side of a chemical equation), and the substances found at the end of the reaction are known as the products (usually found on the right side of a chemical equation).
- An arrow is typically drawn between the reactants and products to indicate the direction of the chemical reaction.
- Explore reactions in which chemical bonds are formed and broken with this model.
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Chemical Kinetics and Chemical Equilibrium
- Chemical kinetics is the study of how quickly a chemical reaction occurs and what factors affect its rate.
- Obviously, there are factors that affect the rates of chemical reactions.
- Knowing how quickly a chemical reaction occurs is a crucial factor in how the reaction affects its surroundings and vice versa.
- The interval required for a chemical change or reaction to occur is called the reaction time.
- Discuss which aspects of a reaction are described by chemical kinetics
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Writing Chemical Equations
- A chemical equation expresses a chemical reaction by showing how certain reactants yield certain products.
- A chemical equation is the symbolic representation of a chemical reaction.
- The reactants (the starting substances) are written on the left, and the products (the substances found in the chemical reaction) are written on the right.
- The coefficients next to the symbols of entities indicate the number of moles of a substance produced or used in the chemical reaction.
- A chemical equation consists of the chemical formulas of the reactants (on the left) and the products (on the right).
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Reaction Quotients
- The reaction quotient is a measure of the relative amounts of reactants and products during a chemical reaction at a given point in time.
- The reaction quotient, Q, is a measure of the relative amounts of reactants and products during a chemical reaction at a given point in time.
- By comparing the value of Q to the equilibrium constant, Keq, for the reaction, we can determine whether the forward reaction or reverse reaction will be favored.
- As the reaction proceeds, assuming that there is no energy barrier, the species' concentrations, and hence the reaction quotient, change.
- Calculate the reaction quotient, Q, and use it to predict whether a reaction will proceed in the forward or reverse direction
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The Rate Law
- The rate law for a chemical reaction relates the reaction rate with the concentrations or partial pressures of the reactants.
- The rate law for a chemical reaction is an equation that relates the reaction rate with the concentrations or partial pressures of the reactants.
- The exponents x and y vary for each reaction, and they must be determined experimentally; they are not related to the stoichiometric coefficients of the chemical equation.
- To reiterate, the exponents x and y are not derived from the balanced chemical equation, and the rate law of a reaction must be determined experimentally.
- What is the reaction order?