polyatomic
(adjective)
Of a molecule or ion consisting of three or more atoms.
Examples of polyatomic in the following topics:
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Polyatomic Molecules
- A polyatomic molecule is a single entity composed of at least three covalently-bonded atoms.
- Polyatomic molecules are electrically neutral groups of three or more atoms held together by covalent bonds.
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Lewis Structures for Polyatomic Ions
- Lewis structures for polyatomic ions are drawn by the same methods that we have already learned.
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Formulas of Ionic Compounds
- Polyatomic ions are a set of covalently bonded atoms that have an overall charge, making them an ion.
- When creating ionic compounds with these polyatomic ions, treat them the same way as typical monatomic ions (only one atom).
- The parentheses were used to indicate that OH was a polyatomic ion and came as a "package deal."
- Parentheses are always used when the compound contains multiples of the polyatomic ion.
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Properties of Sulfur
- Sulfur burns with blue flame, is insoluble in water, and forms polyatomic allotropes.
- Sulfur is found is different polyatomic allotropic forms.
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Naming Acids and Bases
- Any polyatomic ion with the suffix "-ate" uses the suffix "-ic" as an acid.
- When you have a polyatomic ion with one more oxygen than the "-ate" ion, then your acid will have the prefix "per-" and the suffix "-ic."
- Most strong bases contain hydroxide, a polyatomic ion.
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Naming Ionic Compounds
- Usually, the positively charged portion consists of metal cations and the negatively charged portion is an anion or polyatomic ion.
- Ions can be single atoms, as the sodium and chlorine in common table salt (sodium chloride), or more complex (polyatomic) groups such as the carbonate in calcium carbonate.
- If either the cation or the anion was a polyatomic ion, the polyatomic ion name is used in the name of the overall compound.
- The polyatomic ion name stays the same.
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Ions
- An ion consisting of a single atom is a monoatomic ion; an ion consisting of two or more atoms is referred to as a polyatomic ion.
- These representations can be thought of as equivalent for monoatomic ions, but the Roman numerals cannot be applied to polyatomic ions.
- Polyatomic and molecular ions can also be formed, generally by gaining or losing elemental ions, such as H+, in neutral molecules.
- Polyatomic ions are generally very unstable and reactive.
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Electron Configuration of Cations and Anions
- Ionization is not limited to individual atoms; polyatomic ions can also be formed.
- Polyatomic and molecular ions are often created by the addition or removal of elemental ions such as H+ in neutral molecules.
- The two notations are therefore exchangeable for monatomic ions, but the Roman numerals cannot be applied to polyatomic ions.
- However, it is possible to mix the notations for the individual metal center with a polyatomic complex, as demonstrated using the uranyl ion (UO2) as an example.
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Formulas of Ionic Compounds
- If the anion is a polyatomic ion, its suffix can vary, but is typically either -ate or -ite,as in the cases of sodium phosphate and calcium nitrite, depending on the identity of the ion.
- A lesson on writing formulas for binary ionic compounds as well as ionic compounds containing polyatomic ions.
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Salts that Produce Basic Solutions
- The component ions in a salt can be inorganic; examples include chloride (Cl−), the organic acetate (CH3COO−), and monatomic fluoride (F−), as well as polyatomic ions such as sulfate (SO42−).