Electromotive Force
Electromotive force, also called EMF (denoted and measured in volts) refers to voltage generated by a battery or by the magnetic force according to Faraday's Law of Induction, which states that a time varying magnetic field will induce an electric current.
Electromotive "force" is not considered a force (as force is measured in newtons) but a potential, or energy per unit of charge, measured in volts. Formally, EMF is classified as the external work expended per unit of charge to produce an electric potential difference across two open-circuited terminals. By separating positive and negative charges, electric potential difference is produced, generating an electric field. The created electrical potential difference drives current flow if a circuit is attached to the source of EMF. When current flows, however, the voltage across the terminals of the source of EMF is no longer the open-circuit value, due to voltage drops inside the device due to its internal resistance.
Devices that can provide EMF include electrochemical cells (batteries), thermoelectric devices, solar cells, electrical generators, transformers, and even Van de Graaff generators (examples shown in ).
Examples of generators of electromotive force.
A variety of voltage sources (clockwise from top left): the Brazos Wind Farm in Fluvanna, Texas (credit: Leaflet, Wikimedia Commons); the Krasnoyarsk Dam in Russia (credit: Alex Polezhaev); a solar farm (credit: U.S. Department of Energy); and a group of nickel metal hydride batteries (credit: Tiaa Monto). The voltage output of each depends on its construction and load, and equals emf only if there is no load.
In the case of a battery, charge separation that gives rise to a voltage difference is accomplished by chemical reactions at the electrodes; voltaic cells can be thought of as having a "charge pump" of atomic dimensions at each electrode.
In the case of an electrical generator, a time-varying magnetic field inside the generator creates an electric field via electromagnetic induction, which in turn creates an energy difference between generator terminals. Charge separation takes place within the generator, with electrons flowing away from one terminal and toward the other, until, in the open-circuit case, sufficient electric field builds up to make further movement unfavorable. Again the EMF is countered by the electrical voltage due to charge separation. If a load is attached, this voltage can drive a current. The general principle governing the EMF in such electrical machines is Faraday's law of Induction.
In nature, EMF is generated whenever magnetic field fluctuations occur through a surface. An example of this is the varying Earth magnetic field during a geomagnetic storm, acting on anything on the surface of the planet, like an extended electrical grid.