Le Chatelier's principle
(noun)
The principle used to predict the effect of a change in conditions on a chemical equilibrium.
Examples of Le Chatelier's principle in the following topics:
-
Changes in Temperature
- Changes in temperature shift the equilibrium state of chemical reactions; these changes can be predicted using Le Chatelier's Principle.
- The effect of changes to the equilibrium state can be predicted using Le Chatelier's Principle.
- Le Chatelier's Principle states that when changes are made to a reversible chemical reaction in equilibrium, the system will compensate for that change with a predictable, opposing shift.
- Le Chatelier's Principle predicts that the addition of products or the removal of reactants from a system will reverse the direction of a reaction, while the addition of reactants or the removal of products from a system will push the reaction towards the formation of products.
- Applied to temperature, Le Chatelier's Principle predicts that the addition of heat to a system will cause an opposing reaction in the system to remove heat.
-
Changes in Volume and Pressure
- The effects of changes in volume and pressure on a reversible reaction in chemical equilibrium can be predicted by Le Chatelier's Principle.
- The effects of changes in volume and pressure on chemical equilibrium can be predicted using Le Chatelier's Principle.
- Le Chatelier's Principle states that disturbances to a system in equilibrium can be predicted: opposing shifts in the system will occur to restore equilibrium.
- This principle can be applied to changes in temperature, concentration, volume, and pressure.
- Le Chatelier's Principle can be used to predict the response of a reversible chemical reaction to a change in the system.
-
Le Chatelier's Principle
- Le Chatelier's principle states that changes to an equilibrium system will result in a predictable shift that will counteract the change.
- Le Chatelier's principle is an observation about chemical equilibria of reactions.
- By Le Chatelier's principle, increasing the temperature will shift the equilibrium to the right, producing more NO2.
- This lesson shows how Le Chatelier's principle predicts changes in an equilibrium.
- Recall factors that Le Chatelier's principle states will affect the equilibrium of a system
-
Changes in Concentration
- The effect of changes in the concentration of products and reactants in a reversible reaction can be predicted by Le Chatelier's Principle.
- This principle has a variety of names; in chemistry it is known as Le Chatelier's principle.
- Using Le Chatelier's principle, we can predict that the amount of methanol will increase, decreasing the total change in CO.
-
The Common Ion Effect
- The common ion effect can be explained by Le Chatelier's principle of chemical equilibrium:
- According to Le Chatelier's principle, addition of more ions alters the equilibrium and shifts the reaction to favor the solid or deionized form.
-
Solid Solubility and Temperature
- This temperature dependence is sometimes referred to as retrograde or inverse solubility, and exists when a salt's dissolution is exothermic; this can be explained because, according to Le Chatelier's principle, extra heat will cause the equilibrium for an exothermic process to shift towards the reactants.
-
Effect of a Common Ion on Solubility
- This is because Le Chatelier's principle states the reaction will shift toward the left (toward the reactants) to relieve the stress of the excess product.
-
Preparing a Buffer Solution with a Specific pH
- When some strong acid (more H+) is added to an equilibrium mixture of the weak acid and its conjugate base, the equilibrium is shifted to the left, in accordance with Le Chatelier's principle.